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Pilot project “Polymer flooding in Bockstedt”

The biopolymer will be tested over the next three years in a small part of the Bockstedt field. Water mixed with Schizophyllan will be injected into the reservoir and the effects on production from the surrounding wells will be observed. The findings will reveal how well the biopolymer performs and whether it is able to cope with the difficult conditions in the crude oil reservoir. 

These will include the physical stress the biopolymer is exposed to when its flows through the tight interconnections in the rock pore system. These interconnections, termed pore throats, are just one twentieth to one hundredth of a millimeter wide – thinner than a human hair.

Schizophyllan in field testing

After almost two years of research in the BASF labs, Wintershall now aims for the first time to test the biopolymer in an oil field to verify whether it is able to improve oil production. In the rural district of Diepholz, in northern Germany, the Bockstedt crude oil field was chosen for this field test, scheduled to last three years. 

Oil production in Bockstedt and in the neighboring oil fields of Aldorf and Düste have had a long tradition. Since the 1950’s domestic crude oil has been recovered there  and the one millionth ton of crude was produced in the region back in 1958. One year later, the work was expanded to include gas production with the discovery of the gas reserves in Eyelstedt.

A strong team:
cooperation between Wintershall and BASF

Developing schizophyllan is a complicated task which can only be mastered with an efficient and dedicated team. Hence, Wintershall has brought a strong partner on board: the parent company, BASF.



The world’s largest chemicals company has great expertise and years of experience in the field of white biotechnology where microorganisms and enzymes are used to make chemical and biochemical products – for example by means of fermentation, which is also used for the production of schizophyllan. The manufacture of polymers is one of the key fields of white biotechnology. So it goes without saying that the researchers at BASF are indispensable for the development of the biopolymer schizophyllan. A team of about 70 staff from Wintershall and BASF are concentrating their efforts on the fungus and the biopolymer that it produces. The team of researchers is investigating questions such as how long the fermentation takes, how much sugar and how much oxygen the fungus needs for the production of the polymer in close cooperation. Their overriding objective is to optimize production and to make the biopolymer suitable for use in the oil deposit.

The biopolymer in 3D

The secret is the molecular structure: the stability of the biopolymer Schizophyllan is impressively shown in our 3D-model which can be "touched" and twisted and therefore be seen from all sides with your mouse.

With anaglyph spectacles You can experience the Schizophyllan-molecule in a more exciting way.


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Optimal environment

Keeping bacteria away from the polymer is also a challenge in actual production. To provide the biopolymer in the desired quantity and quality, the production process must run smoothly and without any disruption from foreign organisms. To ensure quality, the polymer which is produced at BASF in Ludwigshafen is subject to hygiene standards matching,and sometimes in excess, of those used within the food industry. 

Our solution

Schizophyllan has excellent properties for use in oil production. For instance, it is not deterred by high heat or too much salt in the reservoir. 



Yet there are a few challenges that also have to be overcome with this product: Being a biological product and biodegradable, Schizophyllan is prone to attack by bacteria. As protection against them, a preservative also used in papermaking and in conditioning cooling and warm water is added to it. It is consumed completely while the biopolymer/water mixture flows through the porous rock in the oil reservoir.

The challenge

Deep under the surface the experts are confronted with various challenges: firstly, the biopolymer has to be transported several thousand meters under the surface undamaged. When it gets there it is met by extremely high temperatures which it has to be able to withstand. Furthermore, the deep layers of the earth have a very high salt content. Crude oil production with polymers is nothing new in itself, but many synthetic polymers are not biologically degradable, which means they cannot be used in some places, for example the Norwegian North Sea.

Schizophyllan in use: The idea

The crude oil in many reservoirs is often much more viscous than water. This means that water, being less thick; e can flow through the rock pores far more easily than oil can. Therefore, instead of driving the oil in front of the water as actually desired, the water finds ways over time to squeeze its way past the oil droplets and so sweeps less and less oil along with it.

One way of increasing the amount produced is to reduce the mobility of water in relation to the mobility of oil. This is done by mixing water with a polymer like Schizophyllan whereby the water becomes thicker and presses more oil out of the rock pores as its makes its way through to the reservoir. Due to Schizophyllan, the recovery rate may be increased in future (depending on the reservoir) from around 35 to 45 percent, representing a huge advance.

All production phases at a click

Enhanced oil recovery (EOR)

To extract more oil from the reservoir, enhanced oil recovery (EOR) methods are used in the tertiary stage. 


These methods include steam flooding, which Wintershall has successfully used in Emlichheim on the German/Dutch border for 30 years. High pressure water vapor at a temperature of 300 degrees is forced into the reservoir, trapping the crude oil as the rock heats up, becomes less viscous and ultimately can be extracted more easily. 

The recovery rate is increased from the customary level of 35 percent to up to 45 percent due to this technology.  





A similar increased recovery rate can be achieved with polymer flooding, whereby synthetic polymers or biopolymers like Schizophyllan are used. The principle of polymer flooding differs from that of steam flooding.  Instead of the oil being made more viscous, the water that is pressed in is thickened so that more oil can be driven out of the reservoir. But how exactly does that work?

Secondary production

The secondary phase of production is when the water is  pressed into the reservoir through injection wells in the oil field to maintain the reservoir’s natural pressure as its falls. In this way, a further ten to 20 percent of the oil can be extracted. Some 30 to 40 percent is usually the maximum. The rest remains in the rock pores. 

Primary production

In the first phase, termed primary production, the oil virtually flows to the surface by itself as a result of the natural pressure of the reservoir, however only around 10 percent of it is recovered in this way. Depending on the reservoir, a further five to ten percent can be extracted using traditional pumping technology, such as the familiar ‘nodding donkeys’. 

There is no sea of oil

It is very difficult getting this important and valuable raw material out of the ground – oil is not located in underground seas which can be pumped dry, but usually enclosed in porous rocks such as sandstone or limestone and in salt water. Furthermore, these rock surfaces are  sealed by impermeable layers such as shale or salt. The oil has to be pressed from the rock pores at great technical cost and effort and then transported to the surface. 

Treasure of the deep

Crude oil is found underground and was created millions of years ago. During the warm geological ages, strong algae growth in shallow seas and lakes produced enormous amounts of organic waste. Some of this waste was enclosed in the earth’s crust and, deprived of oxygen and under high pressure, turned into oil over millions of years.



The depth at which oil is located differs greatly – from fifty, several hundred or several thousand meters. For example, Mittelplate, Germany’s largest oil field, is between 2,000 to 3,000 meters below the Wattenmeer with oil haing been produced there since the beginning of 1987. 

Why do we need oil?

Crude oil is the most important raw material for modern industrialized nations. Aside  from being used as fuel, it is the most important basic material for the chemical industry as it used in almost all plastics, detergents, solvents, drugs, cosmetics, waxes or paints, lacquers and varnishes. Oil is also found within 40 percent of textiles and one liter of oil is used for making a CD or DVD and the cover.

The fungus and crude oil

How this valuable raw material is produced, why oil is so important and why our fungus plays such an important role is all revealed in the next chapter.

Eco-friendly? Of course!

Schizophyllan is a real boon in oil production: As the product is heat-resistant and salt-tolerant, it still works effectively in reservoirs with high temperatures and salt concentrations – this is a great advantage given that these conditions are found within half of all the world’s reservoirs. 


Equally as important is the fact that Schizophyllan is extremely eco-friendly. That is because the biopolymer is fully biodegradable – a true natural product. 


The benefits of the fungus have long been recognized in other parts of the world: Schizophyllan is used in South America as a dietary supplement and medicinally in Asia to strengthen the immune system. 


Due to its outstanding environmental compatibility, this biological product can even be used in oil production in highly sensitive ecosystems such as the ocean. This provides a particular advantage in countries like Norway which require that all substances used in offshore production must be biodegradable. 

What is a biopolymer?

There are various types of polymers. With synthetic polymers, the molecule chains are created in chemical reactors. In contrast, a biopolymer is created in a natural biological process – like in brewing beer. In the case of Schizophyllan, the fungus Schizophyllum commune produces the molecule chains itself. The gel-like substance Schizophyllan is made up of a sequence of about 25,000 sugar components. 


In order for it to be used for oil production, BASF exclusively makes the thickening agent in a complex process on behalf of Wintershall. The fungus and a sugar solution are stirred in a fermenter for more than two weeks and aerated with oxygen. The fungus produces the biopolymer in this process. The Schizophyllan is then separated completely from the fungus and cleansed in several stages. The biopolymer is then used in the oil field.

What is a polymer?

The word “polymer” comes from the Greek language meaning “many parts”. A polymer is therefore a chain of molecules having identical units. Polymers turn up just about everywhere in our day-to-day life. One of their main functions is as a thickening agent, for example, in toothpastes and cosmetic articles, where they make liquid substances viscous or gel-like.



Their role is comparable in crude oil production whereby they thicken the water which presses more oil out of pores.

The fungus – a closer inspection

Everything depends on it; the fungus Schizophyllum commune. The white cotton wool-like structure produces the biopolymer Wintershall aims to use to increase crude oil production. The brown fruiting body merely serves for the reproduction of the biopolymer.

Natural wonder from the forestThe fungus which helps in crude oil production

Wintershall is currently developing an eco-friendly technology that could significantly improve crude oil production. The concept is supplied by nature with the key to success being a simple fungus. 

Dead tree – new life

Wintershall is cooperating with BASF on what is currently its largest research project – and at its heart is a simple fungus: Schizophyllum commune.

The fungus with the common name ‘Split Gill’ can be found on dead wood in coniferous and deciduous forests all over the world and seeks out the sunniest and driest places. It essentially feeds off oxygen and various carbon sources, such as sugar. As it grows, it generates a biopolymer – a biological thickening agent it needs for developing, amongst other things, its own cell walls.   

A strong team: Wintershall and BASF

Bernd Leonhardt, Project Manager at Wintershall: “We already had the idea of maximizing crude oil production with the help of a fungus back in the 1980’s. Then, a few years ago we decided to bring the project to life. At the same time we knew that we needed a strong partner to get this technology ready for the market. And what could possibly make more sense than bringing our parent company, BASF, on board?”


Dr. Tobias Käppler (left) and Bernd Leonhardt (right)

Dr. Tobias Käppler, Project Coordinator at BASF: “BASF conducted a thorough analysis of these innovative methods, after which it was clear for the company that we could harness our expertise in the field of biotechnology for this project. Microorganisms such as fungi and their application in biotechnological processes is a field we are well acquainted with. However, we still faced some challenges, but managed to overcome these together. That is also what is so fascinating about this project: we are venturing into new territory every day, no two days are the same.”

Bernd Leonhardt: “That is why good cooperation is tremendously important. The exchange of know-how, goal-orientated work, a dedicated team which enjoys the work… it is only when all these criteria are in place that the project can succeed. All that always worked magnificently in our team of Wintershall and BASF staff.”

Dr. Tobias Käppler: “I can certainly confirm that: Exploring fungus with Wintershall is an exciting project with a fantastic team.”

How does the Fungus help us?

Wintershall is carefully studying this polymer, which was christened Schizophyllan by its producer, because it can be used in the production of oil. When injected into the water the gelatin-like substance thickens the water of the deposit to increase output. 


The water then forces more oil out of the deposit and to the surface because it no longer flows past the valuable raw material so easily. Due to this process, the recovery rate from reservoirs can be enhanced significantly.

Copying nature

Learning from nature is worthwhile and it is often how researchers develop solutions response to technical challenges. 

One well-known example is the lotus effect, where water and dirt are repelled on certain surfaces – a phenomenon that can be observed on the leaves of lotus flowers and is today exploited, for instance, in the production of washbasins.



Wintershall has also understood that nature can be harnessed for technical innovation. The company is currently developing an environmentally compatible technology that could significantly raise the recovery rate of reservoirs – and nature is playing the key role in this process.

Questions to the expert

Bernd Leonhardt, Project Manager of the schizophyllan project at Wintershall, answers your questions.
Do you have any more questions on schizophyllan, EOR techniques or polymer flooding? 

 Then simply send us an e-mail with your questions.

Does the use of this polymer have any effect on the environment?

Oil production with Schizophyllan is absolutely eco-friendly. For example, the field test with the biodegradable polymer proved it had no impact on drinking water. Schizophyllan is to be used at a depth of 1,300 meters, where the oil is located along with the salt water in the rock pores. Neither the polymer, nor the oil, will come into contact with drinking water. 

How does this work?: The geological layer holding the crude oil and salt water is separated from our drinking water by many impermeable rock layers that have existed for millions of years. Among other things, they consist of shale or anhydride, which is related to gypsum. A substance that is introduced at a depth of 1,300 m cannot therefore reach a far higher level where drinking water is located – up to 50 meters below groundwater in the case of Bockstedt. The distance between the drinking water and the crude oil reservoir is therefore 1,250 meters – over one kilometer. 

How do you ensure the environment is protected?

Making sure that the seal between the groundwater and rock layers remains intact is a core task of crude oil and natural gas production and requires responsible action to protect the environment. To ensure the protection of the environmentat the well is secured by steel pipes cemented into the rock and strictly monitored by Wintershall and the competent supervisory authorities. The supervisory authorities control and approve all activities related to the production of oil and gas.

What is the time frame for the test in Bockstedt?

The field test in Bockstedt is divided into two phases: The first stage of the pilot-project “Polymer flooding in Bockstedt” will run until mid-2012 and envisages preparation for the field test at Rüssener Heerweg south of Bockstedt. This will involved sinking three new wells and constructing surface facilities, such as storage buildings, mixing equipment and measurement systems. The biopolymer will then be added and its behavior in the reservoir will be observed. Wintershall has earmarked two years to complete the second phase.  







 
Development work will continue at Wintershall and BASF alongside the field test at Bockstedt. This is because an additional plant will have to be built at BASF’s campus in Ludwigshafen in order for sufficient quantities of the biopolymer to be produced.  

When will schizophyllan be used to produce oil?

It will still be some time before the product can be used in Wintershall’s reservoirs to improve oil production. Yet for Wintershall, Schizophyllan is a product that has a future as in the future the biopolymer can help recover up to 45 percent of the crude oil in reservoirs (amounting to 10 percent more than at present). Technology developed in Germany would thus improve oil production all over the world – and above all set new standards for environmental friendliness. 
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